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姉妹を想うが故に風太郎とは反発してる。
I am a bit confused by the とは where I would have expected a に/には. I don't quite know what function the と serves in this case and how the meaning would differ from に/には.

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とは is both directional(S and 風太郎 反発 each other) but には is single directional(Only S 反発 to 風太郎). It's difference between と and に. So, in this sentence, と/に/には can also be expected.

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