From what I can see people are forced to use the term of a younger or older brother/sister oneesan, oniisan, etc.
But what do you call a brother or sister if they're the same age as you?
I think that even twins, born only moments apart, are considered to be older and younger based on who was born first. So even if you're both twenty years old, the normal rules apply.
That's why you can say things like 双子のお兄さん "older twin brother".